Tak, możesz zrobić sprawę:
select case when noOfGirls=0 then noOfBoys
else round(noOfBoys/noOfGirls) end as ration
from student;
Ale prawdopodobnie chcesz:
select case when noOfGirls=0 then 1
else round(noOfBoys/noOfGirls) end as ration
from student;